Studies on the phase behavior of perfluoropolyether carboxylic acids and their salts: Observation of a stunning temperature-dependent color effect for the birefringence in the pyridinium salt system

Literature Information

Publication Date 2001-07-04
DOI 10.1039/B102776J
Impact Factor 3.676
Authors

J. Würtz, J. Meyer, H. Hoffmann


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Abstract

The phase behavior of a series of perfluoropolyether (PFPE) carboxylic acids and their salts (tetramethyl ammonium and pyridinium) was studied. The small solubility of the pure acids in water could be significantly enhanced by preparation of these salts that proved to be highly surface active. The most interesting result of our studies was a temperature-dependent color effect that appears for a multilamellar vesicle phase of a PFPE pyridinium salt between crossed polarizers. That effect is caused by a wavelength dependence of the birefringence in this system (dispersion) and the change in the dispersion with temperature is probably due to a change in the adsorption of the pyridinium ions to the surface of the surfactant aggregates.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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