On the variation of the electric quadrupole moment with internuclear distance and the atom–diatom long-range electrostatic interaction energy
Literature Information
S. P. J. Rodrigues, A. J. C. Varandas
The electric quadrupole moment of several first-row diatomic hydrides has been calculated as a function of the internuclear distance. The calculated values have been fitted to a general analytical function which covers from the united-atom to the separated-atoms limits. A discussion on the atom–diatom electrostatic interaction energy is presented, and the validity of the classical optimized quadrupole moment method tested.
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