Transparent semi- and full-interpenetrating polymer networks based on uralkyd–polymethyl methacrylate

Literature Information

Publication Date 2000-03-01
DOI 10.1039/A908388J
Impact Factor 3.676
Authors

Vilas Athawale, Sachin Raut


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Abstract

Transparent two-component semi- and full-interpenetrating polymer networks (IPNs) of soybean–oil based uralkyd resin (UA) and polymethyl methacrylate (PMMA) were synthesized by the sequential technique. The elastomers obtained were characterized with respect to their mechanical properties such as tensile strength, percent elongation and hardness (shore A). The apparent densities of these samples were determined and compared. Glass transition studies were carried out using differential scanning calorimetry (DSC). The thermal characterization of the elastomers was undertaken with the aid of thermogravimetric analysis (TGA). Phase morphology was studied by scanning electron microscopy (SEM). The effect of the compositional variation on the above mentioned properties was examined. The elongation % showed higher values in the case of all the semi-IPNs as compared to the full-IPNs and showed optimum values for 50% UA–50% PMMA full- and semi-IPNs.

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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