The FT microwave spectrum of benzo[b]thiophene: first application of a new heatable beam nozzle
Literature Information
A new beam nozzle for a cavity FT microwave spectrometer has been developed that can be heated, even in close contact with massive aluminum mirrors, to temperatures up to 473 K (200°C). It has been used to evaporate a sufficient amount of benzo[b]thiophene to record and assign its rotational spectrum in the vibronic ground state of the normal and the 34S isotopomer. Spectra of some excited vibrational states of the normal isotopic species were also found and assigned. In both cases rotational and quartic centrifugal distortion constants are reported.
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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.










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