The investigation of mixed monolayers adsorbed from solution: octane and nonane mixtures on graphite

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DOI 10.1039/A906184C
Impact Factor 3.676
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Abstract

The combination of sensitive calorimetry, incoherent elastic neutron scattering and neutron diffraction has been used to demonstrate the formation of solid layers containing both octane and nonane adsorbed onto graphite from the binary alkane mixture. This combination of methods allow us to characterise the adsorbed layer in some detail including the absolute composition and melting temperature as a function of solution composition. The evidence presented here suggests that the two alkanes exist on the surface as patches of pure material not as a single crystal incorporating both alkanes.

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DOI: 10.1039/CS98514BP021

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DOI: 10.1039/CS98110FP005

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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