Bromotricarbonyl(tetrahydrofuran)rhenium(I) dimer | CAS No. 54082-95-0

Bromotricarbonyl(tetrahydrofuran)rhenium(I) dimer

Basic Information

CAS Number

54082-95-0

Molecular Formula

C14H16Br2O8Re2

Molecular Weight

844.49 g/mol

AD

Basic Physical Properties

[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].C1CCOC1.C1CCOC1.Br[Re].Br[Re]

InChI

InChI=1S/2C4H8O.6CO.2BrH.2Re/c2*1-2-4-5-3-1;6*1-2;;;;/h2*1-4H2;;;;;;;2*1H;;/q;;;;;;;;;;2*+1/p-2

InChIKey

GARJHXMUDDMPBU-UHFFFAOYSA-L

LogP

0.08129

Topological Polar Surface Area

0.0 Ų

Hydrogen Bond Donor/Acceptor

0 / 0

Complexity

34.8

Safety Information

View Safety Information

Hazard Statement

H301 Toxic if swallowed
Acute toxicity, oral
H311 Toxic in contact with skin
Acute toxicity, dermal
H331 Toxic if inhaled
Acute toxicity, inhalation

Synonyms & References

English

  • bromotricarbonyl(tetrahydrofuran)rheniu&amp
  • bromorhenium,carbon monoxide,oxolane
  • Dibromohexacarbonylbis(tetrahydrofuran)dirhenium
  • 54082-95-0 (name error)
  • BROMOTRICARBONYL(TETRAHYDROFURAN)RHENIU&
  • Bromotricarbonyl(tetrahydrofuran)rhenium(I) dimer
  • DTXSID60469891
  • 54082-95-0
  • bromorhenium;carbon monoxide;oxolane
  • BROMOTRICARBONYL(TETRAHYDROFURAN)RHENIUM(I)DIMER

FAQ

What are the physical and chemical properties of Bromotricarbonyl(tetrahydrofuran)rhenium(I) dimer (CAS: 54082-95-0)?

Bromotricarbonyl(tetrahydrofuran)rhenium(I) dimer (CAS: 54082-95-0) is a dimeric compound with a molecular weight of approximately 532.07 g/mol. It is poorly soluble in water but soluble in organic solvents like tetrahydrofuran. The compound exhibits strong reactivity towards nucleophiles and can undergo substitution reactions. It is typically crystalline at room temperature.

How is Bromotricarbonyl(tetrahydrofuran)rhenium(I) dimer (CAS: 54082-95-0) typically synthesized?

Bromotricarbonyl(tetrahydrofuran)rhenium(I) dimer (CAS: 54082-95-0) is synthesized through a multi-step process involving the reaction of rhenium(I) bromide with tetrahydrofuran under controlled conditions. The yield is typically high, and the selectivity is excellent. Catalysts like triphenylphosphine are commonly used to improve the reaction efficiency and purity of the product.

What industries use Bromotricarbonyl(tetrahydrofuran)rhenium(I) dimer (CAS: 54082-95-0)?

Bromotricarbonyl(tetrahydrofuran)rhenium(I) dimer (CAS: 54082-95-0) is used in the pharmaceutical industry for catalytic reactions, in the polymer industry for the synthesis of specific polymers, and in the semiconductor industry for doping applications. It is also utilized in sensor technology for its unique reactivity and selectivity.

What precautions should be taken when handling Bromotricarbonyl(tetrahydrofuran)rhenium(I) dimer (CAS: 54082-95-0)?

When handling Bromotricarbonyl(tetrahydrofuran)rhenium(I) dimer (CAS: 54082-95-0), it is essential to wear appropriate personal protective equipment (PPE) such as gloves, goggles, and a lab coat. Work should be conducted in a well-ventilated fume hood to minimize exposure. Accidental spills should be cleaned up immediately, and appropriate safety data sheets (SDS) should be consulted for specific handling and disposal procedures.

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