Tetradecahedral Cu@Ag core–shell powder with high solid-state dewetting and oxidation resistance for low-temperature conductive paste

Literature Information

Publication Date 2023-12-13
DOI 10.1039/D3TA06483B
Impact Factor 12.732
Authors

Yulian Zeng, Zhenzhen Chen, Zheng Lu, Mengfei Ni, Chen-Wei Peng, Zipeng Wang, Hua Sun, Xiaodong Su


View Original

Abstract

The high cost of metallization using low-temperature cured Ag paste is one of the factors limiting the industrial deployment of silicon heterojunction (SHJ) solar cells, which can be mitigated by developing Ag-coated Cu (Cu@Ag) core–shell powders to replace Ag powders. Yet, a large number of grain boundaries in the Ag shell induce solid-state dewetting of the Ag shell and provide oxygen channels to the Cu core, thus adversely affecting the long-term stability and efficient operation of SHJ modules. Here, a novel tetradecahedral Cu@Ag core–shell powder with large Ag shell grains, meaning low grain boundary density, was fabricated by electroless plating, and the formation mechanism of Ag shells with large grains and smooth surfaces was revealed. The tetradecahedral Cu@Ag powder resists dewetting even after heat treatment at 250 °C for 30 min in air and survives oxidization at room temperature for at least 3 months in air, showing better dewetting and oxidation resistance. Experiments and simulations show that the electrode prepared with tetradecahedral Cu@Ag powder has higher electrical conductivity than that prepared with conventional spherical Cu@Ag powder. This study represents a promising strategy for improving the reliability and conductivity of Cu@Ag powder used for the metallization of SHJ solar cells.

Related Literature

Unexpected protonation state of Glu197 discovered from simulations of tacrine in butyrylcholinesterase

Xiao Wan, Yuan Yao, Lei Fang, Junjun Liu

2018-05-08 Paper

DOI: 10.1039/C8CP01566J

Eliminating common biases in modelling the electrical conductivity of carbon nanotube–polymer nanocomposites

Linh Trong Hoang, Siu Ning Leung, Zheng Hong Zhu

2018-04-12 Communication

DOI: 10.1039/C8CP01715H

Viable aromatic BenHn stars enclosing a planar hypercoordinate boron or late transition metal

Xue-Feng Zhao, Jia-Jia Li, Hai-Ru Li, Caixia Yuan, Xinxin Tian, Si-Dian Li, Yan-Bo Wu, Zhi-Xiang Wang

2018-02-19 Paper

DOI: 10.1039/C7CP06955C

Oxygen-induced high diffusion rate of magnesium dopants in GaN/AlGaN based UV LED heterostructures

Paweł Piotr Michałowski, Sebastian Złotnik, Jakub Sitek, Krzysztof Rosiński, Mariusz Rudziński

2018-05-01 Paper

DOI: 10.1039/C8CP01470A

Effects of CNT size on the desalination performance of an outer-wall CNT slit membrane

Elisa Y. M. Ang, Teng Yong Ng, Rongming Lin, Zishun Liu, K. R. Geethalakshmi

2018-04-19 Paper

DOI: 10.1039/C8CP01191E

Theoretical study on mesoscopic-size impurity effects in the charge separation process of organic photocells

Motomichi Tashiro, Takahito Nakajima

2018-05-21 Paper

DOI: 10.1039/C7CP08125A

Correction: Insights into the enhanced CeN triple bond in the HCeN molecule

Zhen Pu, Wenjie Yu, Soumendra K. Roy, Chaoyang Li, Bingyun Ao, Tianwei Liu, Maobing Shuai, Xuefeng Wang

2018-05-21 Correction

DOI: 10.1039/C8CP91766C

You might also like

Compound Q&A

What precautions should be taken when handling 2-Chloro-1,2-bis(4-methylphenyl)ethanone (CAS: 71193-32-3)?

When handling 2-Chloro-1,2-bis(4-methylphenyl)ethanone (CAS: 71193-32-3), it is ...

71193-32-32-Chloro-1,2-bis(4-m...
Compound Q&A

What industries use 4-Ethoxy-3-(5-methyl-4-oxo-7-propyl-1,4-dihydroimidazo[5,1-f][1,2,4]triazin-2-yl)benzenesulfonyl chloride (CAS: 224789-26-8)?

4-Ethoxy-3-(5-methyl-4-oxo-7-propyl-1,4-dihydroimidazo[5,1-f][1,2,4]triazin-2-yl...

224789-26-84-Ethoxy-3-(5-methyl...
Compound Q&A

How should Methyl 3-Oxo-4-Androsten-17-Carboxylate (CAS: 2681-55-2) be stored?

Methyl 3-Oxo-4-Androsten-17-Carboxylate (CAS: 2681-55-2) should be stored in a c...

2681-55-2Methyl 3-Oxo-4-Andro...
Compound Q&A

What are the main uses of (R)-3-Amino-4-(3-hexylphenylamino)-4-oxobutylphosphonic acid (CAS: 909725-61-7)?

(R)-3-Amino-4-(3-hexylphenylamino)-4-oxobutylphosphonic acid is primarily used i...

909725-61-7(R)-3-Amino-4-(3-hex...
Compound Q&A

What regulatory guidelines apply to 2-Methyl-2-propanyl 3-amino-3-carbamoyl-1-azetidinecarboxylate (CAS: 1254120-14-3)?

2-Methyl-2-propanyl 3-amino-3-carbamoyl-1-azetidinecarboxylate (CAS: 1254120-14-...

1254120-14-32-Methyl-2-propanyl ...
Compound Q&A

Are there alternatives to (E)-4-(tert-Butoxy)-4-oxobut-2-enoic acid (CAS: 135355-96-3) in synthesis?

There are alternative reagents that can be used in synthesis instead of (E)-4-(t...

135355-96-3(E)-4-(tert-Butoxy)-...
Compound Q&A

What are the physical and chemical properties of [2-(3-Chlorophenyl)-1,3-thiazol-4-yl]methanol (CAS: 121202-20-8)?

[2-(3-Chlorophenyl)-1,3-thiazol-4-yl]methanol (CAS: 121202-20-8) is a crystallin...

121202-20-8[2-(3-Chlorophenyl)-...
166249-17-8Methyl (2S)-[(4S)-2,...
Compound Q&A

What is the market or research trend for 1-Bromo-2-isocyanatoethane (CAS: 42865-19-0)?

The market for 1-Bromo-2-isocyanatoethane (CAS: 42865-19-0) is driven by its use...

42865-19-01-Bromo-2-isocyanato...
Compound Q&A

What are the main uses of 4-Nitro-D-phenylalanine hydrochloride (CAS: 147065-06-3)?

4-Nitro-D-phenylalanine hydrochloride (CAS: 147065-06-3) is primarily used in re...

147065-06-34-Nitro-D-phenylalan...

Source Journal

Journal of Materials Chemistry A

Journal of Materials Chemistry A
CiteScore: 19.5
Self-citation Rate: 4.7%
Articles per Year: 2211

Journal of Materials Chemistry A, B & C cover high quality studies across all fields of materials chemistry. The journals focus on those theoretical or experimental studies that report new understanding, applications, properties and synthesis of materials. The journals have a strong history of publishing quality reports of interest to interdisciplinary communities and providing an efficient and rigorous service through peer review and publication. The journals are led by an international team of Editors-in-Chief and Associate Editors who are all active researchers in their fields. Journal of Materials Chemistry A, B & C are separated by the intended application of the material studied. Broadly, applications in energy and sustainability are of interest to Journal of Materials Chemistry A, applications in biology and medicine are of interest to Journal of Materials Chemistry B, and applications in optical, magnetic and electronic devices are of interest to Journal of Materials Chemistry C. More than one Journal of Materials Chemistry journal may be suitable for certain fields and researchers are encouraged to submit their paper to the journal that they feel best fits for their particular article. Example topic areas within the scope of Journal of Materials Chemistry A are listed below. This list is neither exhaustive nor exclusive. Artificial photosynthesis Batteries Carbon dioxide conversion Catalysis Fuel cells Gas capture/separation/storage Green/sustainable materials Hydrogen generation Hydrogen storage Photocatalysis Photovoltaics Self-cleaning materials Self-healing materials Sensors Supercapacitors Thermoelectrics Water splitting Water treatment

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.