A PEDOT:PSS nanocomposite film doped with black phosphorus modified with silver nanoparticles for wearable photothermoelectric generators

Literature Information

Publication Date 2023-10-26
DOI 10.1039/D3TA05836K
Impact Factor 12.732
Authors

Chia-Hao Tsai, Shih-Hung Tung, Jhih-Min Lin


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Abstract

Photothermoelectric (PTE) materials have gained significant attention as a promising avenue for converting light into electricity. Herein, the PTE properties of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) are enhanced by introducing black phosphorus nanosheets (BP NSs) modified with silver nanoparticles (Ag@BP). Under 100 mW cm−2 illumination, the resulting PEDOT:PSS/Ag@BP nanocomposite film (P_Ag@BP) exhibits an output voltage of 528.4 μV compared to 300.9 μV for the PEDOT:PSS film. This is attributed to (i) the enhanced photothermal performance of P_Ag@BP, which generates a temperature difference of 18 °C under 100 mW cm−2 illumination compared to 10 °C for the PEDOT:PSS film and (ii) the enhanced thermoelectric performance of P_Ag@BP, with an increased power factor of 107.2 μW m−1 K−2 compared to 32.9 μW m−1 K−2 for the PEDOT:PSS film. Moreover, a photothermoelectric generator (PTEG) consisting of 36 legs of P_Ag@BP exhibits an open circuit voltage of 16.1 mV, a short circuit current of 47.9 μA, and an output power of 192.6 nW under 120 mW cm−2 illumination. Furthermore, when the PTEG is worn on the forearm and exposed to sunlight, it generates an output voltage of 9.2 mV, thus showcasing its potential application in wearable energy harvesting devices.

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Source Journal

Journal of Materials Chemistry A

Journal of Materials Chemistry A
CiteScore: 19.5
Self-citation Rate: 4.7%
Articles per Year: 2211

Journal of Materials Chemistry A, B & C cover high quality studies across all fields of materials chemistry. The journals focus on those theoretical or experimental studies that report new understanding, applications, properties and synthesis of materials. The journals have a strong history of publishing quality reports of interest to interdisciplinary communities and providing an efficient and rigorous service through peer review and publication. The journals are led by an international team of Editors-in-Chief and Associate Editors who are all active researchers in their fields. Journal of Materials Chemistry A, B & C are separated by the intended application of the material studied. Broadly, applications in energy and sustainability are of interest to Journal of Materials Chemistry A, applications in biology and medicine are of interest to Journal of Materials Chemistry B, and applications in optical, magnetic and electronic devices are of interest to Journal of Materials Chemistry C. More than one Journal of Materials Chemistry journal may be suitable for certain fields and researchers are encouraged to submit their paper to the journal that they feel best fits for their particular article. Example topic areas within the scope of Journal of Materials Chemistry A are listed below. This list is neither exhaustive nor exclusive. Artificial photosynthesis Batteries Carbon dioxide conversion Catalysis Fuel cells Gas capture/separation/storage Green/sustainable materials Hydrogen generation Hydrogen storage Photocatalysis Photovoltaics Self-cleaning materials Self-healing materials Sensors Supercapacitors Thermoelectrics Water splitting Water treatment

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