Modular preparation of functional bimetallic spinels from metal–organic frameworks: a deep exploration from macro and micro perspectives

Literature Information

Publication Date 2023-11-21
DOI 10.1039/D3TA05478K
Impact Factor 12.732
Authors

Qi Li, Yuan Zhu, Min Cheng, Li Du, Meihua Zhao, Gaoxia Zhang, Guangfu Wang, Wenjun Wang, Hongda Liu, Yongxi Chen, Wenjun Xiao


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Abstract

In recent years, bimetallic spinels (AB2X4) have played significant roles in energy and environmental remediation due to their excellent redox capacity. However, the disadvantages of traditional bimetallic spinels (blocky structure, low specific surface area, and poor reaction kinetics) limit their performances. Noting the controllable chemical composition, high specific surface area and strong design capability of metal–organic frameworks (MOFs), bimetallic spinels synthesized using them as sacrificial templates inherit the structural advantages of the parent materials and improve the inherent defects of traditional bimetallic spinels. These provide great opportunities for the application and development of bimetallic spinels. Therefore, this review presents two synthetic strategies for MOF-derived bimetallic spinels. Special emphasis is placed on the performance advantages of MOF-derived bimetallic spinels due to their unique variations. Based on this, recent advances in the energy field and environmental remediation as well as the mechanism of action are systematically reviewed. Finally, some issues and outlooks on their design are presented. This review aims to provide a systematic reference for the design of MOF-derived bimetallic spinels.

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Source Journal

Journal of Materials Chemistry A

Journal of Materials Chemistry A
CiteScore: 19.5
Self-citation Rate: 4.7%
Articles per Year: 2211

Journal of Materials Chemistry A, B & C cover high quality studies across all fields of materials chemistry. The journals focus on those theoretical or experimental studies that report new understanding, applications, properties and synthesis of materials. The journals have a strong history of publishing quality reports of interest to interdisciplinary communities and providing an efficient and rigorous service through peer review and publication. The journals are led by an international team of Editors-in-Chief and Associate Editors who are all active researchers in their fields. Journal of Materials Chemistry A, B & C are separated by the intended application of the material studied. Broadly, applications in energy and sustainability are of interest to Journal of Materials Chemistry A, applications in biology and medicine are of interest to Journal of Materials Chemistry B, and applications in optical, magnetic and electronic devices are of interest to Journal of Materials Chemistry C. More than one Journal of Materials Chemistry journal may be suitable for certain fields and researchers are encouraged to submit their paper to the journal that they feel best fits for their particular article. Example topic areas within the scope of Journal of Materials Chemistry A are listed below. This list is neither exhaustive nor exclusive. Artificial photosynthesis Batteries Carbon dioxide conversion Catalysis Fuel cells Gas capture/separation/storage Green/sustainable materials Hydrogen generation Hydrogen storage Photocatalysis Photovoltaics Self-cleaning materials Self-healing materials Sensors Supercapacitors Thermoelectrics Water splitting Water treatment

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