Heterostructured MoP/CoMoP2 embedded in an N, P-doped carbon matrix as a highly efficient cooperative catalyst for pH-universal overall water splitting
Literature Information
Cong Liu, Boxu Gao, Tianlan Yan, Yahong Zhang, Xiaoming Cao, Qingsheng Gao, Yi Tang
To design and build effective electrocatalysts for water splitting is a key challenge, but hardly any non-noble metal catalysts can match the performance of Pt at cathodes and Ir or Ru at anodes. The synergistic combination of non-noble metal catalysts could be a better option for overall water splitting (OWS). Herein, a heterostructured electrocatalyst of MoP/CoMoP2 nanoparticles embedded in an N, P-doped carbon matrix (MoP/CoMoP2@NPC) was fabricated via reticular chemistry. The results indicate that, due to the cooperative effect of MoP/CoMoP2 interfaces and phosphorus vacancies, MoP/CoMoP2@NPC shows extraordinary efficiency and robust stability for hydrogen/oxygen evolution reactions (HER/OER) and OWS in a wide pH range. This work could offer a promising interface-engineering approach to develop and build effective cooperative electrocatalysts for the sustainable production of hydrogen.
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DOI: 10.1039/A607993H
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Journal of Materials Chemistry A

Journal of Materials Chemistry A, B & C cover high quality studies across all fields of materials chemistry. The journals focus on those theoretical or experimental studies that report new understanding, applications, properties and synthesis of materials. The journals have a strong history of publishing quality reports of interest to interdisciplinary communities and providing an efficient and rigorous service through peer review and publication. The journals are led by an international team of Editors-in-Chief and Associate Editors who are all active researchers in their fields. Journal of Materials Chemistry A, B & C are separated by the intended application of the material studied. Broadly, applications in energy and sustainability are of interest to Journal of Materials Chemistry A, applications in biology and medicine are of interest to Journal of Materials Chemistry B, and applications in optical, magnetic and electronic devices are of interest to Journal of Materials Chemistry C. More than one Journal of Materials Chemistry journal may be suitable for certain fields and researchers are encouraged to submit their paper to the journal that they feel best fits for their particular article. Example topic areas within the scope of Journal of Materials Chemistry A are listed below. This list is neither exhaustive nor exclusive. Artificial photosynthesis Batteries Carbon dioxide conversion Catalysis Fuel cells Gas capture/separation/storage Green/sustainable materials Hydrogen generation Hydrogen storage Photocatalysis Photovoltaics Self-cleaning materials Self-healing materials Sensors Supercapacitors Thermoelectrics Water splitting Water treatment










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