Cylindrical brushes with ionized side chains: Scaling theory revisited

Literature Information

Publication Date 2023-10-26
DOI 10.1039/D3SM00727H
Impact Factor 3.679
Authors

Ekaterina B. Zhulina


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Abstract

We revisit the classic scaling model of a cylindrical polyelectrolyte (PE) brush focusing on molecular brushes with stiff backbones and dispersions of polymer-decorated nanorods. Based on the blob representation we demonstrate that similarly to the case of planar PE brushes, separation of intra- and intermolecular repulsions between charges leads to novel scaling regimes for cylindrical PE brushes in salt-added solution and a sharper decrease in its thickness versus salt concentration dependence. These theoretical predictions may inspire further comprehensive experimental research and computer simulations of synthetic and biopolyelectrolyte cylindrical brushes.

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Soft Matter

Soft Matter
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