Three-dimensional lead iodide perovskites based on complex ions

Literature Information

Publication Date 2023-09-02
DOI 10.1039/D3MA00202K
Impact Factor 0
Authors

Hebin Wang, Haolin Lu, Teng Wang, Yuki Haruta, Xingzhan Wei, Guichuan Xing, Makhsud I. Saidaminov, Yecheng Zhou, Guankui Long


View Original

Abstract

Lead-halide perovskites have demonstrated outstanding optical, electrical, and spintronic properties and have made significant breakthroughs in many fields, especially in solar cells. Although substantial efforts have been devoted to developing novel 3D perovskites with a lower band gap towards the application in perovskite solar cells, none of them succeeded. Here we propose three novel 3D lead iodide perovskites with complex ions, Cu(NH3)2PbI3, Ag(NH3)2PbI3 and Au(NH3)2PbI3. Based on the optimized structures, formation and dissociation energies, phonon spectra, and ab initio molecular dynamics simulations, it is found that Ag(NH3)2PbI3 and Au(NH3)2PbI3 are kinetically and thermodynamically stable. Furthermore, Ag(NH3)2PbI3 and Au(NH3)2PbI3 exhibit large absorption coefficients, suitable optical band gaps and small electron effective masses, which are very promising towards application in perovskite solar cells.

Related Literature

Identification of synergistic Cu/V redox pair in VCu:AlPO-5; a comparison with VCu:ZSM-5

Katrine Lie Bøyesen, Tina Kristiansen, Karina Mathisen

2014-08-12 Paper

DOI: 10.1039/C4CP02503B

Back cover

Cover

DOI: 10.1039/C4CP90140A

Raman mapping investigation of chemical vapor deposition-fabricated twisted bilayer graphene with irregular grains

Yuming Chen, Lijuan Meng, Weiwei Zhao, Zheng Liang, Xing Wu, Haiyan Nan, Zhangting Wu, Shan Huang, Litao Sun, Jinlan Wang, Zhenhua Ni

2014-08-26 Paper

DOI: 10.1039/C4CP03386H

Inside front cover

Cover

DOI: 10.1039/C4CP90123A

Non-radiative decay paths in rhodamines: new theoretical insights

Umberto Raucci, Paolo A. Netti, Ilaria Ciofini

2014-07-14 Paper

DOI: 10.1039/C4CP02622E

Photocatalytic generation of solar fuels from the reduction of H2O and CO2: a look at the patent literature

Stefano Protti, Angelo Albini, Nick Serpone

2014-07-28 Perspective

DOI: 10.1039/C4CP02828G

PCCP’s 15th anniversary

2014-05-01 Editorial

DOI: 10.1039/C4CP90054E

The adsorption behaviour of CH4 on microporous carbons: effects of surface heterogeneity

Dongliang Jin, Xiaoqing Lu, Mingmin Zhang, Shuxian Wei, Qing Zhu, Xiaofan Shi, Yang Shao, Weili Wang, Wenyue Guo

2014-04-03 Paper

DOI: 10.1039/C3CP55107E

A DFT study on the reaction mechanism of dimerization of methyl methacrylate catalyzed by N-heterocyclic carbene

Yunxia Li, Yanyan Zhu, Wenjing Zhang, Donghui Wei, Yingying Ran, Qilin Zhao, Mingsheng Tang

2014-07-31 Paper

DOI: 10.1039/C4CP02186J

The dynamic action mechanism of small cationic antimicrobial peptides

J. J. Lopez Cascales, R. D. Porasso

2014-08-28 Paper

DOI: 10.1039/C4CP02537G

You might also like

Compound Q&A

What precautions should be taken when handling 2-Chloro-1,2-bis(4-methylphenyl)ethanone (CAS: 71193-32-3)?

When handling 2-Chloro-1,2-bis(4-methylphenyl)ethanone (CAS: 71193-32-3), it is ...

71193-32-32-Chloro-1,2-bis(4-m...
Compound Q&A

What industries use 4-Ethoxy-3-(5-methyl-4-oxo-7-propyl-1,4-dihydroimidazo[5,1-f][1,2,4]triazin-2-yl)benzenesulfonyl chloride (CAS: 224789-26-8)?

4-Ethoxy-3-(5-methyl-4-oxo-7-propyl-1,4-dihydroimidazo[5,1-f][1,2,4]triazin-2-yl...

224789-26-84-Ethoxy-3-(5-methyl...
Compound Q&A

How should Methyl 3-Oxo-4-Androsten-17-Carboxylate (CAS: 2681-55-2) be stored?

Methyl 3-Oxo-4-Androsten-17-Carboxylate (CAS: 2681-55-2) should be stored in a c...

2681-55-2Methyl 3-Oxo-4-Andro...
Compound Q&A

What are the main uses of (R)-3-Amino-4-(3-hexylphenylamino)-4-oxobutylphosphonic acid (CAS: 909725-61-7)?

(R)-3-Amino-4-(3-hexylphenylamino)-4-oxobutylphosphonic acid is primarily used i...

909725-61-7(R)-3-Amino-4-(3-hex...
Compound Q&A

What regulatory guidelines apply to 2-Methyl-2-propanyl 3-amino-3-carbamoyl-1-azetidinecarboxylate (CAS: 1254120-14-3)?

2-Methyl-2-propanyl 3-amino-3-carbamoyl-1-azetidinecarboxylate (CAS: 1254120-14-...

1254120-14-32-Methyl-2-propanyl ...
Compound Q&A

Are there alternatives to (E)-4-(tert-Butoxy)-4-oxobut-2-enoic acid (CAS: 135355-96-3) in synthesis?

There are alternative reagents that can be used in synthesis instead of (E)-4-(t...

135355-96-3(E)-4-(tert-Butoxy)-...
Compound Q&A

What are the physical and chemical properties of [2-(3-Chlorophenyl)-1,3-thiazol-4-yl]methanol (CAS: 121202-20-8)?

[2-(3-Chlorophenyl)-1,3-thiazol-4-yl]methanol (CAS: 121202-20-8) is a crystallin...

121202-20-8[2-(3-Chlorophenyl)-...
166249-17-8Methyl (2S)-[(4S)-2,...
Compound Q&A

What is the market or research trend for 1-Bromo-2-isocyanatoethane (CAS: 42865-19-0)?

The market for 1-Bromo-2-isocyanatoethane (CAS: 42865-19-0) is driven by its use...

42865-19-01-Bromo-2-isocyanato...
Compound Q&A

What are the main uses of 4-Nitro-D-phenylalanine hydrochloride (CAS: 147065-06-3)?

4-Nitro-D-phenylalanine hydrochloride (CAS: 147065-06-3) is primarily used in re...

147065-06-34-Nitro-D-phenylalan...
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.