From biomass to C4 chemicals: selective transformation of bio-based furans to succinic anhydride in the presence of oxygen

Literature Information

Publication Date 2023-09-22
DOI 10.1039/D3CY01152F
Impact Factor 6.119
Authors

Xiaoqian Gao, Xinli Tong, RuiChen Liu, Yi Zhang


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Abstract

Succinic anhydride (SAN), a C4 bulk chemical, is selectively produced from bio-based furans with a simple metalloporphyrin as the catalyst under visible light. Typically, 99% conversion of furfuryl alcohol with 87.7% selectivity toward SAN was obtained in the presence of zinc(II) tetraphenyl porphyrin (ZnTPP) as the photocatalyst. It is confirmed that the generation of singlet oxygen (1O2) plays a crucial role in the transformation of furanic derivatives.

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Catalysis Science & Technology

Catalysis Science & Technology
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