Selective oxidation of substituted phenols with Co–N–C catalysts fabricated via low temperature heat treatment
Literature Information
Bairui Guo, Zhongtian Du, Xiaoyu Shen, Mengjing Han, Yanbin Zhao, Jingjie Luo
Co–N–C catalysts were fabricated for efficient oxidation of mono-phenols after undergoing pyrolysis at 250–400 °C. 2,3,6-Trimethylphenol could be facilely oxidized into 2,3,5-trimethyl-1,4-benzoquinone with dioxygen. CoO, Co3O4 or metallic Co particles were excluded as catalytic active species, and active Co(II) species with N/O coordination were dispersed on disordered carbonaceous materials.
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