Fractional Marcus–Hush–Chidsey–Yakopcic current–voltage model for redox-based resistive memory devices

Literature Information

Publication Date 2023-12-01
DOI 10.1039/D3CP04177H
Impact Factor 3.676
Authors

G. V. Paradezhenko, D. V. Prodan


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Abstract

We propose a circuit-level model combining the Marcus–Hush–Chidsey electron current equation and the Yakopcic equation for the state variable for describing resistive switching memory devices of the structure metal–ionic conductor–metal. We extend the dynamics of the state variable originally described by a first-order time derivative by introducing a fractional derivative with an arbitrary order between zero and one. We show that the extended model fits with great fidelity the current–voltage characteristic data obtained on a Si electrochemical metallization memory device with Ag–Cu alloy.

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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