(10)-Oriented β-Ga2O3 grown on (0001) sapphire by halide vapor phase epitaxy: growth and structural characterizations

Literature Information

Publication Date 2023-10-05
DOI 10.1039/D3CE00831B
Impact Factor 3.545
Authors

Wanli Xu, Yuewen Li, Bin Li, Xiangqian Xiu, Hong Zhao, Zili Xie, Tao Tao, Peng Chen, Bin Liu, Rong Zhang, Youdou Zheng


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Abstract

In general, β-Ga2O3 films with (01) out-of-orientation have been widely obtained and reported on (0001) sapphire substrates by various growth methods. In this paper, the unusual (10)-oriented β-Ga2O3 films have been epitaxially grown on (0001) sapphire substrates with high crystal-quality under Ga-rich conditions by halide vapor phase epitaxy (HVPE). The out-of-plane epitaxial relationship as (10) β-Ga2O3//(0001) α-Al2O3 has been confirmed by XRD and HRTEM analysis. Under most growth conditions, β-Ga2O3 films exhibit the coexistence of (10) and (01) out-of-plane orientation domains, and increasing the growth temperatures and HCl flow-rates can enhance the growth of (10)-oriented β-Ga2O3. Off-angled (0001) sapphire substrates with off-angles (Δa) toward 〈110〉 have been introduced to control the in-plane domains. It was indicated that the (01)-oriented domains have been gradually eliminated with increasing the off-angles, and pure (10)-oriented β-Ga2O3 films with the best crystal quality reported so far have been obtained while the off-angle was ∼7°. The decrease of the domain boundaries and defects caused by the in-plane rotational domains have led to the improvement of the crystal quality of the as-grown films.

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CrystEngComm

CrystEngComm
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