Engineering surface lattice hydroxyl groups toward highly efficient photocatalytic methane coupling

Literature Information

Publication Date 2023-12-22
DOI 10.1039/D3CC04645A
Impact Factor 6.222
Authors

Zili Ma, Yihong Chen, Chao Gao


View Original

Abstract

Nb3O7(OH) containing abundant surface lattice hydroxyl groups, combining with loaded Au nanoparticles as the cocatalyst, was employed as a photocatalyst enabling highly efficient photocatalytic CH4 coupling to C2H6 under mild conditions. In situ spectroscopy technique revealed that the surface lattice hydroxyl groups play a vital role in promoting the activation of CH4 to produce the methoxy intermediates, contributing to significantly enhanced catalytic performance for CH4 conversion.

Related Literature

The reduced [2Fe-2S] clusters in adrenodoxin and Arthrospira platensisferredoxin share spin density with proteinnitrogens, probed using 2D ESEEM

Sergei A. Dikanov, Rimma I. Samoilova, Reinhard Kappl, Antony R. Crofts, Jürgen Hüttermann

2009-07-01 Paper

DOI: 10.1039/B904597J

Radiofrequency polarization effects in zero-field electron paramagnetic resonance

Christopher T. Rodgers, C. J. Wedge, Stuart A. Norman, Philipp Kukura, Karen Nelson, Neville Baker, Kevin B. Henbest, P. J. Hore

2009-07-03 Communication

DOI: 10.1039/B906102A

Growth of CdS nanoparticles on the aligned carbon nanotubes

A. V. Okotrub, I. P. Asanov, S. V. Larionov, T. G. Leonova, L. G. Bulusheva

2010-07-07 Paper

DOI: 10.1039/C000189A

Fluorescence of sanguinarine: spectral changes on interaction with amino acids

Marika Janovská, Martin Kubala, Vilím Šimánek, Jitka Ulrichová

2010-08-03 Paper

DOI: 10.1039/B925828K

Rhodamines in the gas phase: cations, neutrals, anions, and adducts with metal cations

Konstantin Chingin, Roman M. Balabin, Konstantin Barylyuk, Huanwen Chen, Vladimir Frankevich, Renato Zenobi

2010-08-10 Paper

DOI: 10.1039/C000807A

Supramolecular interactions of fullerenes with (Cl)Fe- and Mn porphyrins. A theoretical study

Meng-Sheng Liao, John D. Watts, Ming-Ju Huang

2009-05-18 Paper

DOI: 10.1039/B904782D

Mapping of the organization of p-nitroaniline in SAPO-5 by second-harmonic generation microscopy

Jasper Van Noyen, Bert F. Sels, Pierre A. Jacobs, Thierry Verbiest, Dirk E. De Vos

2010-08-16 Communication

DOI: 10.1039/C0CP00257G

Contents and Highlights in Chemical Technology

Front/Back Matter

DOI: 10.1039/B913645M

Dynamic nuclear polarization coupling factors calculated from molecular dynamics simulations of a nitroxide radical in water

Deniz Sezer, M. J. Prandolini, Thomas F. Prisner

2009-07-06 Paper

DOI: 10.1039/B905709A

You might also like

Compound Q&A

What precautions should be taken when handling 2-Chloro-1,2-bis(4-methylphenyl)ethanone (CAS: 71193-32-3)?

When handling 2-Chloro-1,2-bis(4-methylphenyl)ethanone (CAS: 71193-32-3), it is ...

71193-32-32-Chloro-1,2-bis(4-m...
Compound Q&A

What industries use 4-Ethoxy-3-(5-methyl-4-oxo-7-propyl-1,4-dihydroimidazo[5,1-f][1,2,4]triazin-2-yl)benzenesulfonyl chloride (CAS: 224789-26-8)?

4-Ethoxy-3-(5-methyl-4-oxo-7-propyl-1,4-dihydroimidazo[5,1-f][1,2,4]triazin-2-yl...

224789-26-84-Ethoxy-3-(5-methyl...
Compound Q&A

How should Methyl 3-Oxo-4-Androsten-17-Carboxylate (CAS: 2681-55-2) be stored?

Methyl 3-Oxo-4-Androsten-17-Carboxylate (CAS: 2681-55-2) should be stored in a c...

2681-55-2Methyl 3-Oxo-4-Andro...
Compound Q&A

What are the main uses of (R)-3-Amino-4-(3-hexylphenylamino)-4-oxobutylphosphonic acid (CAS: 909725-61-7)?

(R)-3-Amino-4-(3-hexylphenylamino)-4-oxobutylphosphonic acid is primarily used i...

909725-61-7(R)-3-Amino-4-(3-hex...
Compound Q&A

What regulatory guidelines apply to 2-Methyl-2-propanyl 3-amino-3-carbamoyl-1-azetidinecarboxylate (CAS: 1254120-14-3)?

2-Methyl-2-propanyl 3-amino-3-carbamoyl-1-azetidinecarboxylate (CAS: 1254120-14-...

1254120-14-32-Methyl-2-propanyl ...
Compound Q&A

Are there alternatives to (E)-4-(tert-Butoxy)-4-oxobut-2-enoic acid (CAS: 135355-96-3) in synthesis?

There are alternative reagents that can be used in synthesis instead of (E)-4-(t...

135355-96-3(E)-4-(tert-Butoxy)-...
Compound Q&A

What are the physical and chemical properties of [2-(3-Chlorophenyl)-1,3-thiazol-4-yl]methanol (CAS: 121202-20-8)?

[2-(3-Chlorophenyl)-1,3-thiazol-4-yl]methanol (CAS: 121202-20-8) is a crystallin...

121202-20-8[2-(3-Chlorophenyl)-...
166249-17-8Methyl (2S)-[(4S)-2,...
Compound Q&A

What is the market or research trend for 1-Bromo-2-isocyanatoethane (CAS: 42865-19-0)?

The market for 1-Bromo-2-isocyanatoethane (CAS: 42865-19-0) is driven by its use...

42865-19-01-Bromo-2-isocyanato...
Compound Q&A

What are the main uses of 4-Nitro-D-phenylalanine hydrochloride (CAS: 147065-06-3)?

4-Nitro-D-phenylalanine hydrochloride (CAS: 147065-06-3) is primarily used in re...

147065-06-34-Nitro-D-phenylalan...

Source Journal

Chemical Communications

Chemical Communications
CiteScore: 8.6
Self-citation Rate: 4.7%
Articles per Year: 2458

ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.