Alkylsulfonium salts for the photochemical desulphurizative functionalization of heteroarenes
Literature Information
Publication Date
2021-11-24
DOI
10.1039/D1QO01570B
Impact Factor
5.281
Authors
Xiaolong Zhu, Xuan Li, Enjie Zhu, Qirong Deng, Xiuyan Song, Jian Lv
View Original
Abstract
The development of new versatile alkylation reagents that can be transformed from diverse available chemical raw materials is highly desirable. Here, an efficient, metal-free organic photoredox-catalyzed direct alkylation of heteroarenes via a desulphurization strategy using alkylsulfonium salts as alkylation reagents under mild conditions has been described for the first time. The inexpensive and efficient organic photoredox-catalyzed method offers a new and useful strategy for constructing various biologically interesting heteroarenes in the fields of synthetic and pharmaceutical chemistry, and extends the scope of the still limited sulfonium salt photochemistry.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
5,7,8'-Trihydroxy-2',2'-dimethyl-2'H,4H-3,6'-bichromen-4-one
CAS Number:
129280-33-7
Molecular Formula:
C20H16O6
2-Methyl-2-propanyl (3R,5S)-6-chloro-3,5-dihydroxyhexanoate
CAS Number:
154026-93-4
Molecular Formula:
C10H19ClO4
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