Cobalt-catalyzed C8–H sulfonylation of 1-naphthylamine derivatives with sodium sulfinates
Literature Information
Publication Date
2021-08-11
DOI
10.1039/D1QO00975C
Impact Factor
5.281
Authors
Yucong Sun, Cancan Feng, Peisong Wang, Fan Yang, Yangjie Wu
View Original
Abstract
A facile and efficient protocol for cobalt-catalyzed regioselective C8–H sulfonylation of 1-naphthylamine derivatives with sodium sulfinates, affording sulfonylated naphthylamines in moderate to good yields, is described. The reaction exhibits broad functional group tolerance and high regioselectivity. Note that the addition of a catalytic amount of NFSI or Selectfluor as the auxiliary ligand would enhance the reaction efficiency. Furthermore, the picolinamide moiety as a bidentate directing group likely plays a key role in this regioselective transformation.
Related Literature
Royal Agricultural Society of England. Annual Report of the Consulting Chemist for 1940
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DOI: 10.1039/AN941660334A
Department of Scientific and Industrial Research. Report of the National Physical Laboratory for 1939
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DOI: 10.1039/AN940650413B
Queensland. Report of the Government Analyst for the year ending June, 1932
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DOI: 10.1039/AN933580098A
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
![Ethyl 5-[({[(2-methyl-2-propanyl)oxy]carbonyl}amino)methyl]-1,2-oxazole-3-carboxylate structure](https://static.chemtradehub.com/structs/253/253196-37-1-8450.webp "Ethyl 5-[({[(2-methyl-2-propanyl)oxy]carbonyl}amino)methyl]-1,2-oxazole-3-carboxylate structure")
Ethyl 5-[({[(2-methyl-2-propanyl)oxy]carbonyl}amino)methyl]-1,2-oxazole-3-carboxylate
CAS Number:
253196-37-1
Molecular Formula:
C12H18N2O5
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