Cu-Catalyzed highly selective silylation and borylation of alkenylsulfonium salts
Literature Information
Publication Date
2021-08-06
DOI
10.1039/D1QO00922B
Impact Factor
5.281
Authors
Rong Xie, Jie Zhu, Yinhua Huang
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Abstract
A Cu-catalyzed highly selective silylation and borylation of alkenylsulfonium salts under mild conditions is reported. The reaction provides easy access to various alkenylsilanes and alkenylboranes by forming a C–Si/B bond at the alkenyl moiety of alkenylsulfonium salts with high stereoselectivity, a broad substrate scope and tolerance to various functional groups.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
3-(3-Carboxyphenyl)-5-(trifluoromethyl)benzoic acid
CAS Number:
1261930-96-4
Molecular Formula:
C15H9F3O4
![[3-Formyl-5-(trifluoromethoxy)phenyl]boronic acid structure](https://static.chemtradehub.com/structs/145/1451393-39-7-aebb.webp "[3-Formyl-5-(trifluoromethoxy)phenyl]boronic acid structure")
[3-Formyl-5-(trifluoromethoxy)phenyl]boronic acid
CAS Number:
1451393-39-7
Molecular Formula:
C8H6BF3O4
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