Phthalimide-based-SSCF3 reagent for enantioselective dithiotrifluoromethylation
Literature Information
Publication Date
2021-01-22
DOI
10.1039/D1QO00001B
Impact Factor
5.281
Authors
Jianrong Liu
View Original
Abstract
An electrophilic phthalimide-based-SSCF3 reagent was designed and prepared for straightforward SSCF3 incorporation of diverse β-keto esters in natural products, pharmaceuticals and biological molecules. The asymmetric dithiotrifluoromethylation was achieved with a good to excellent enantioselectivity, catalyzed by a cinchona-alkaloid-based catalyst (DHQD)2PHAL via an ammonium-hydrogen-bonded induction mode.
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Organic Chemistry Frontiers
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