High molar mass poly(ricinoleic acid) via entropy-driven ring-opening metathesis polymerization
Literature Information
Publication Date
2021-03-23
DOI
10.1039/D1PY00185J
Impact Factor
5.582
Authors
Marc A. Hillmyer
View Original
Abstract
High molar mass poly(ricinoleic acid) with a weight average molar mass over 400 kg mol−1 was synthesized via entropy-driven ring-opening metathesis polymerization of mono-, di- and mixed macrolactones of ricinoleic acid using a Grubbs second-generation catalyst and fully characterized. The high molar mass was achieved by reducing the catalyst loading, and the resultant polymer product had a very low level of ruthenium (36 ppm as Ru based on G2 feed), was colorless and exhibited a high decomposition temperature without purification steps aimed at removing ruthenium.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
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CAS Number:
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Molecular Formula:
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