Probing the interactions of GlcNH2 with boric acid via NMR spectroscopy

Literature Information

Publication Date 2021-07-06
DOI 10.1039/D1CP01795K
Impact Factor 3.676
Authors

Rui Liu, Jiayu Lv, Luqi Liu, Zhenzhou Zhang, Yingxiong Wang, Xianglin Hou


View Original

Abstract

The essential role of boronic esters in controlling both the direction and selectivity of chemical reactions as well as their significant function in catalytic activity have been demonstrated for industrially important processes. The specific interaction analyses of the monosaccharide GlcNH2 with boric acid are of interest since monosaccharides serve as model systems for the more sophisticated carbohydrate molecules. The interaction of GlcNH2 with boric acid was systematically investigated by numerous NMR techniques. A 1 : 1 chelate boron complex coordinated at the cis-1,2 position of GlcNH2 was identified as the major species in DMSO-d6 solution via1H and 13C INEPT DOSY NMR spectroscopy. This specific boron nitrogen coordination mechanism was further supported by the 1H–15N HSQC spectra. Variations in the spin–lattice relaxation times (T1) of the 13C1 nucleus also provided quantitative data regarding this non-covalent interactions. This is an application of 1H, 13C INEPT DOSY, 1H–15N HSQC, and relaxation methods to study such aggregations in solutions. These methods have potential applications in the characterization of reactive intermediates in biomass conversions.

Related Literature

Stable and high-rate overcharge protection for rechargeable lithium batteries

Bin Wang, Thomas J. Richardson, Guoying Chen

2013-04-02 Paper

DOI: 10.1039/C3CP50992C

Front cover

Cover

DOI: 10.1039/C3CP90048G

Front cover

Cover

DOI: 10.1039/C3CP90042H

Photovoltaic devices and characterization of a dodecyloxybenzothiadiazole-based copolymer

Purna P. Maharjan, Qiliang Chen, Lianjie Zhang, Olusegun Adebanjo, Nirmal Adhikari, Swaminathan Venkatesan, Prajwal Adhikary, Bjorn Vaagensmith, Qiquan Qiao

2013-03-14 Paper

DOI: 10.1039/C3CP51070K

Investigation of the nanomechanical properties of β-Si3N4nanowires under three-point bending via molecular dynamics simulation

Xuefeng Lu, Hongjie Wang, Meng Chen, Lei Fan, Chao Wang, Shuhai Jia

2013-02-27 Communication

DOI: 10.1039/C3CP50372K

Back matter

Front/Back Matter

DOI: 10.1039/C3CP90053C

A statistical approach for analyzing the development of 1H multiple-quantum coherence in solids

Yuuki Mogami, Yasuto Noda, Hiroto Ishikawa, K. Takegoshi

2013-04-12 Paper

DOI: 10.1039/C3CP43778G

Specific many-electron effects in X-ray spectra of simple metals and graphene

R. E. Ovcharenko, I. I. Tupitsyn, E. P. Savinov, E. N. Voloshina, B. Paulus, Yu. S. Dedkov, A. S. Shulakov

2013-03-14 Paper

DOI: 10.1039/C3CP44304C

Density-induced molecular arrangements of water inside carbon nanotubes

M. Sadeghi

2013-03-18 Paper

DOI: 10.1039/C3CP44563A

Mesoscopic modelling of frustration in microemulsions

Magali Duvail, Jean-François Dufrêche, Lise Arleth, Thomas Zemb

2013-03-18 Paper

DOI: 10.1039/C3CP43981J

You might also like

Compound Q&A

Is 4-Benzyl-2,2-dimethylmorpholine (CAS: 84761-04-6) safe?

4-Benzyl-2,2-dimethylmorpholine is generally considered safe when handled under ...

84761-04-64-Benzyl-2,2-dimethy...
Compound Q&A

What is (5,6-Dimethoxy-3-pyridinyl)boronic acid (CAS: 1346526-61-1)?

(5,6-Dimethoxy-3-pyridinyl)boronic acid is a chemical compound with the molecula...

1346526-61-1(5,6-Dimethoxy-3-pyr...
Compound Q&A

How is 1,1,3,3-Tetramethyl-1,3-bis(2-methyl-2-propanyl)disiloxane (CAS: 67875-55-2) typically synthesized?

1,1,3,3-Tetramethyl-1,3-bis(2-methyl-2-propanyl)disiloxane is synthesized throug...

67875-55-21,1,3,3-Tetramethyl-...
Compound Q&A

What are the main uses of (2R,4S)-1-Boc-4-methylpyrrolidine-2-carboxylic acid (CAS: 1018818-04-6)?

(2R,4S)-1-Boc-4-methylpyrrolidine-2-carboxylic acid is primarily used as a build...

1018818-04-6(2R,4S)-1-Boc-4-meth...
Compound Q&A

What precautions should be taken when handling 2,3-Dichloroacrylonitrile (CAS: 22410-58-8)?

When handling 2,3-Dichloroacrylonitrile, it is crucial to wear appropriate perso...

22410-58-82,3-Dichloroacryloni...
Compound Q&A

How should (S)-1-(o-Tolyl)ethanamine hydrochloride (CAS: 1332832-16-2) be stored?

(S)-1-(o-Tolyl)ethanamine hydrochloride should be stored in a cool, dry place to...

1332832-16-2(S)-1-(o-Tolyl)ethan...
Compound Q&A

What are the physical and chemical properties of Benzyl [1-(hydroxyamino)-1-imino-2-methyl-2-propanyl]carbamate (CAS: 518047-98-8)?

Benzyl [1-(hydroxyamino)-1-imino-2-methyl-2-propanyl]carbamate (CAS: 518047-98-8...

518047-98-8Benzyl [1-(hydroxyam...
Compound Q&A

What industries use 2-Methyloxazole-5-carbaldehyde (CAS: 885273-42-7)?

2-Methyloxazole-5-carbaldehyde is used in the pharmaceutical industry for the sy...

885273-42-72-Methyloxazole-5-ca...
Compound Q&A

What is the market or research trend for 2-Methyl-2-propanyl 4-[(1S)-1-hydroxyethyl]-1-piperidinecarboxylate (CAS: 389889-82-1)?

The market for 2-Methyl-2-propanyl 4-[(1S)-1-hydroxyethyl]-1-piperidinecarboxyla...

389889-82-12-Methyl-2-propanyl ...
Compound Q&A

Is 1-Butyl-3-methylpyridinium bromide (CAS: 26576-85-2) safe?

1-Butyl-3-methylpyridinium bromide is generally considered safe for laboratory u...

26576-85-21-Butyl-3-methylpyri...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.