The role of the three body photodissociation channel of water in the evolution of dioxygen in astrophysical applications

Literature Information

Publication Date 2021-04-06
DOI 10.1039/D1CP00565K
Impact Factor 3.676
Authors

Suming An, Kaijun Yuan, Rex T. Skodje


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Abstract

A recent experiment at the Dalian Coherent Light Source (DCLS) has provided measurements of the partial cross sections for the photodissociation of water vapor over an unprecedented range of wavelengths in the vacuum ultraviolet (VUV) region. It was found that the three body dissociation channel, H + H + O(3P/1D), becomes prominent at wavelengths shorter than the Lyman α-line at 121.6 nm. The present work explores the kinetic consequences of this discovery for several astrophysically motivated examples. The irradiation of a dilute low-temperature gas by unscreened solar radiation, similar to early stage photochemical processing in a comet coma, shows significant increase in the production of O2-molecules at shorter times, <1 day, that might physically correspond to the photochemical reaction zone of the coma. Several examples of planetary atmospheres show increased O-atom production at high altitudes but relatively little modification of the equilibrium O2 concentrations predicted by conventional models.

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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