A self-assembled tetrathiafulvalene box
Literature Information
Publication Date
2021-01-08
DOI
10.1039/D0QO01543A
Impact Factor
5.281
Authors
Vincent Croué, Olivier Alévêque, Eric Levillain, Magali Allain, Cécile Mézière, Vincent Carré, Frédéric Aubriet, Zoia Voïtenko, Sébastien Goeb, Marc Sallé
View Original
Abstract
A M8L2 metalla-cage constructed through coordination-driven self-assembly from a quinonato bis-ruthenium complex and an electron-rich tetrathiafulvalene (TTF) tetrapyridyl ligand is depicted. In this molecular box, both TTF units are highly bent and are separated by a distance as short as 3.48 Å in the solid state. This system offers a unique opportunity to study the electronic interactions occurring between two TTF units facing each other in a conformationally rigid environment.
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Organic Chemistry Frontiers
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