Carbon dioxide-promoted palladium-catalyzed dehydration of primary allylic alcohols: access to substituted 1,3-dienes
Literature Information
Publication Date
2020-12-30
DOI
10.1039/D0QO01465F
Impact Factor
5.281
Authors
Yan-Kai Huang, Wen-Zhen Zhang, Ke Zhang, Wen-Le Wang, Xiao-Bing Lu
View Original
Abstract
1,3-Dienes are versatile synthons and important monomers. Herein we report a carbon dioxide promoted dehydration reaction of primary allylic alcohols to produce substituted 1,3-dienes in good yields. Taking advantage of carbon dioxide as a promoter to facilitate the alcoholic C–O bond cleavage via the formation of an allylic bicarbonate ester, this reaction proceeds under mild conditions.
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Source Journal
Organic Chemistry Frontiers
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7.8
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Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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