Recent developments in palladium-catalyzed C–S bond formation

Literature Information

Publication Date 2020-04-22
DOI 10.1039/D0QO00377H
Impact Factor 5.281
Authors

Jianxiao Li, Shaorong Yang, Wanqing Wu, Huanfeng Jiang


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Abstract

Transition metal-catalyzed C–S bond formation reactions have attracted considerable attention in the recent years. In this regard, palladium-catalyzed C–S bond formation is typically attractive because it can effectively assemble structurally diverse unsymmetrical aryl sulfides and functionalized sulfones under mild conditions with high regioselectivities. In this review, palladium-catalyzed C–S bond formation reactions are summarized and discussed in detail with the focus on sulfenylation and sulfonylation reactions involving aryl/heteroaryl C–H bonds, alkynes, aryl halides, electron-rich benzoic acid derivatives, arylhydrazines, and organosilicon reagents. Some representative synthetic strategies and their transformation application along with reaction mechanisms are also highlighted.

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Organic Chemistry Frontiers

Organic Chemistry Frontiers
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Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

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