Pd(ii)/Ag(i)-Cocatalyzed ortho direct arylation of O-phenylcarbamates with pinacol aryl boronates
Literature Information
Publication Date
2019-03-05
DOI
10.1039/C9QO00227H
Impact Factor
5.281
Authors
Huijun Ma, Tao Wang, Chenying Gao, Guangshen Li, Minghao Zhang
View Original
Abstract
Ortho direct arylation of O-phenylcarbamates using aryl boronates as coupling partners has been realized for the first time in the literature. A mechanistic investigation showed that the Wheland intermediate with ortho C–H remaining after carbopalladation was the key intermediate for further transformation. Isotope competition experiments indicated that C–H cleavage was not involved in the rate-determining step.
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Organic Chemistry Frontiers
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