Coexistence of structurally similar but electronically distinct isomers of delocalized cation radicals as a basis for the development of functional materials

Literature Information

Publication Date 2019-05-07
DOI 10.1039/C9CP02271F
Impact Factor 3.676
Authors

Marat R. Talipov, Esther Steiner


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Abstract

Certain low-symmetry aromatic molecules with a small HOMO/HOMO−1 energy gap might co-exist as electronic isomers in their cation radical states that differ only in bond lengths yet have distinct optical and electronic properties. These electronic isomers are sensitive to the environment and might be used for the development of novel functional materials.

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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