High-speed tracking of fast chemical precipitations
Literature Information
Réka Zahorán, Ákos Kukovecz, Ágota Tóth, Dezső Horváth, Gábor Schuszter
Heterogeneous reactions taking place in the aqueous phase bear significant importance both in applied and fundamental research. Among others, producing solid catalysts, crystallizing biomorphs or pharmaceutically relevant polymorphs, and yielding bottom-up synthesised precipitate structures are prominent examples. To achieve a better control on product properties, reaction kinetics and mechanisms must be taken into account especially in dynamic systems where transport processes are coupled to chemistry. Since the characteristic time scale of numerous precipitation reactions falls below 1 s within the relevant concentration range, unique experimental protocols are needed. Herein we present a high-speed camera supported experimental procedure capable of determining such characteristic time scales in the range of 10 ms to 1 s. The method is validated both experimentally and by performing 3D hydrodynamic simulations.
Recommended Journals

Journal of Chemical Sciences

Herald of the Russian Academy of Sciences

Atomization and Sprays

Chinese Journal of Chemistry

Colloid Journal

Polycyclic Aromatic Compounds

Bioorganic & Medicinal Chemistry

Medicinal Chemistry Research

Journal of Asian Natural Products Research

Critical Reviews in Solid State and Materials Sciences
Related Literature
A computational study on the superionic behaviour of ThO2
P. S. Ghosh, A. Arya, G. K. Dey, N. Kuganathan, R. W. Grimes
DOI: 10.1039/C6CP05794B
High-performance printable hybrid perovskite solar cells with an easily accessible n-doped fullerene as a cathode interfacial layer
Chih-Yu Chang, Bo-Chou Tsai, Yu-Cheng Hsiao, Yu-Ching Huang
DOI: 10.1039/C6CP06486H
Hydrogen abstraction from metal surfaces: when electron–hole pair excitations strongly affect hot-atom recombination
Rémi Pétuya, Fabio Busnengo
DOI: 10.1039/C6CP06222A
Towards understanding the unusual photoluminescence intensity variation of ultrasmall colloidal PbS quantum dots with the formation of a thin CdS shell
Fuqiang Ren, Sarah A. Lindley, Haiguang Zhao, Long Tan, Belete Atomsa Gonfa, Ying-Chih Pu, Fan Yang, Xinyu Liu, François Vidal, Jin Z. Zhang, Dongling Ma
DOI: 10.1039/C6CP05786A
An accurate multi-channel multi-reference full-dimensional global potential energy surface for the lowest triplet state of H2O2
Richard Dawes, Hua Guo
DOI: 10.1039/C6CP06232F
The impact of endohedral atoms on the electronic and optical properties of Au25(SR)18 and Au38(SR)24
DOI: 10.1039/C6CP02691E
Planarity and multiple components promote organic photovoltaic efficiency by improving electronic transport
Matthew B. Goldey, Daniel Reid, Juan de Pablo, Giulia Galli
DOI: 10.1039/C6CP04999K
A comparative study of Ni–Mn layered double hydroxide/carbon composites with different morphologies for supercapacitors
M. Li, F. Liu, X. B. Zhang, J. P. Cheng
DOI: 10.1039/C6CP05119G
Ab initio thermodynamic study of the SnO2(110) surface in an O2 and NO environment: a fundamental understanding of the gas sensing mechanism for NO and NO2
Song-Nam Hong, Yun-Hyok Kye, Chol-Jun Yu, Un-Gi Jong, Gum-Chol Ri, Chang-Song Choe, Kwang-Hui Kim, Ju-Myong Han
DOI: 10.1039/C6CP05433A
You might also like
What precautions should be taken when handling 2-Chloro-1,2-bis(4-methylphenyl)ethanone (CAS: 71193-32-3)?
When handling 2-Chloro-1,2-bis(4-methylphenyl)ethanone (CAS: 71193-32-3), it is ...
What industries use 4-Ethoxy-3-(5-methyl-4-oxo-7-propyl-1,4-dihydroimidazo[5,1-f][1,2,4]triazin-2-yl)benzenesulfonyl chloride (CAS: 224789-26-8)?
4-Ethoxy-3-(5-methyl-4-oxo-7-propyl-1,4-dihydroimidazo[5,1-f][1,2,4]triazin-2-yl...
How should Methyl 3-Oxo-4-Androsten-17-Carboxylate (CAS: 2681-55-2) be stored?
Methyl 3-Oxo-4-Androsten-17-Carboxylate (CAS: 2681-55-2) should be stored in a c...
What are the main uses of (R)-3-Amino-4-(3-hexylphenylamino)-4-oxobutylphosphonic acid (CAS: 909725-61-7)?
(R)-3-Amino-4-(3-hexylphenylamino)-4-oxobutylphosphonic acid is primarily used i...
What regulatory guidelines apply to 2-Methyl-2-propanyl 3-amino-3-carbamoyl-1-azetidinecarboxylate (CAS: 1254120-14-3)?
2-Methyl-2-propanyl 3-amino-3-carbamoyl-1-azetidinecarboxylate (CAS: 1254120-14-...
Are there alternatives to (E)-4-(tert-Butoxy)-4-oxobut-2-enoic acid (CAS: 135355-96-3) in synthesis?
There are alternative reagents that can be used in synthesis instead of (E)-4-(t...
What are the physical and chemical properties of [2-(3-Chlorophenyl)-1,3-thiazol-4-yl]methanol (CAS: 121202-20-8)?
[2-(3-Chlorophenyl)-1,3-thiazol-4-yl]methanol (CAS: 121202-20-8) is a crystallin...
What is the market or research trend for Methyl (2S)-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]{[(4-methylphenyl)sulfonyl]oxy}acetate (CAS: 166249-17-8)?
The market and research trends for Methyl (2S)-[(4S)-2,2-dimethyl-1,3-dioxolan-4...
What is the market or research trend for 1-Bromo-2-isocyanatoethane (CAS: 42865-19-0)?
The market for 1-Bromo-2-isocyanatoethane (CAS: 42865-19-0) is driven by its use...
What are the main uses of 4-Nitro-D-phenylalanine hydrochloride (CAS: 147065-06-3)?
4-Nitro-D-phenylalanine hydrochloride (CAS: 147065-06-3) is primarily used in re...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.




