Cu(i)–SNS complexes for outer-sphere hydroboration and hydrosilylation of carbonyls
Literature Information
Matthew R. Elsby, R. Tom Baker
Two new NHC–Cu(I)-[κ2-SNS] complexes were synthesized to directly compare the bifunctional catalytic activity of a hard amido vs. a soft thiolate donor. The Cu thiolate complex catalyzed ketone hydroboration but not hydrosilylation, while the Cu amido complex is a high-performing outer-sphere carbonyl reduction catalyst using boranes and silanes.
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