A catalyst-controlled switchable reaction of β-keto acids to silyl glyoxylates
Literature Information
Man-Yi Han, Hong Pan, Jing Lin, Wei Li, Pinhua Li
A catalyst-controlled switchable reaction of β-keto acids to silyl glyoxylates was developed under mild conditions, providing two distinct products in good yields. Compared to decarboxylative addition-Brook rearrangement, the decarboxylative addition products could be controlled by using a simple bifunctional organocatalyst thiourea derivative instead of DABCO. This new reaction model of silyl glyoxylates offered a facile and alternative route to organosilicon compounds.
Related Literature
United Provinces and Central Provinces, India. Annual Report of the Chemical Examiner for 1939
DOI: 10.1039/AN940650601A
Proceedings of the Society of Public Analysts and other Analytical Chemists
DOI: 10.1039/AN940650587A
Proceedings of the Society of Public Analysts and other Analytical Chemists
DOI: 10.1039/AN942670001A
Government of Bengal. Annual Report of the Chemical Examiner for 1939
DOI: 10.1039/AN941660202A
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Organic & Biomolecular Chemistry

Organic & Biomolecular Chemistry (OBC) publishes original and high impact research and reviews in organic chemistry. We welcome research that shows new or significantly improved protocols or methodologies in total synthesis, synthetic methodology or physical and theoretical organic chemistry as well as research that shows a significant advance in the organic chemistry or molecular design aspects of chemical biology, catalysis, supramolecular and macromolecular chemistry, theoretical chemistry, mechanism-oriented physical organic chemistry, medicinal chemistry or natural products. Articles published in the journal should report new work which makes a highly-significant impact in the field. Routine and incremental work is generally not suitable for publication in the journal. More details about key areas of our scope are below. In all cases authors should include in their article clear rationale for why their research has been carried out.












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