A degradable cross-linked polymer containing dynamic covalent selenide bond
Literature Information
Publication Date
2017-06-01
DOI
10.1039/C7PY00719A
Impact Factor
5.582
Authors
Weihong Lu, Xiangqiang Pan, Zhengbiao Zhang, Jian Zhu, Nianchen Zhou, Xiulin Zhu
View Original
Abstract
A new method for preparing a degradable cross-linked polymer containing dynamic selenide was demonstrated. 1,2-Bis(2,3,5,6-tetrafluoro-4-vinylphenyl)diselane (FVPDSe) was synthesized and used as a photoinitiator, mediator and dynamic covalent cross-linker to prepare cross-linked polymers via reversible-deactivation radical polymerization with vinyl monomers such as styrene, methyl acrylate, n-butyl acrylate, 2-hydroxyethyl acrylate and methyl methacrylate. After oxidation by hydrogen peroxide, the structure of the cross-linked polymer obtained from the copolymerization of FVPDSe with styrene was carefully analyzed using 1H, 13C, 19F, and 77Se NMR and SEC. In addition, the “livingness” of the obtained cross-linked polymers was also investigated.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
2,2-dideuterio-2-(3,4,5,6-tetradeuterio-2-pyridyl)acetic acid;hydrochloride
CAS Number:
1329799-67-8
Molecular Formula:
C7H2ClD6NO2
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