5-Bromo-2-chloro-N-methoxy-N-methylisonicotinamide
CAS Number:
1256790-08-5
Molecular Formula:
C8H8BrClN2O2
Gold catalyzed Heck-coupling of arenediazonium o-benzenedisulfonimides
Literature Information
Publication Date
2017-12-08
DOI
10.1039/C7OB02624B
Impact Factor
3.876
Authors
Margherita Barbero, Stefano Dughera
View Original
Abstract
Diazonium salts, and precisely arenediazonium o-benzenedisulfonimides, have been used for the first time as efficient electrophilic partners in gold catalyzed Heck-coupling reactions. The synthetic protocol was general, easy and gave the target products in satisfactory yields. Mechanistic insights revealed the fundamental roles of the o-benzenedisulfonimide anion as an electron transfer agent thath promotes a radical pathway that does not require the presence of photocatalysts or external oxidants.
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Source Journal
Organic & Biomolecular Chemistry
CiteScore:
3.4
Self-citation Rate:
10.3%
Articles per Year:
1041
Organic & Biomolecular Chemistry (OBC) publishes original and high impact research and reviews in organic chemistry. We welcome research that shows new or significantly improved protocols or methodologies in total synthesis, synthetic methodology or physical and theoretical organic chemistry as well as research that shows a significant advance in the organic chemistry or molecular design aspects of chemical biology, catalysis, supramolecular and macromolecular chemistry, theoretical chemistry, mechanism-oriented physical organic chemistry, medicinal chemistry or natural products. Articles published in the journal should report new work which makes a highly-significant impact in the field. Routine and incremental work is generally not suitable for publication in the journal. More details about key areas of our scope are below. In all cases authors should include in their article clear rationale for why their research has been carried out.
Recommended Compounds
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5,7-Dihydroxy-3-(4-hydroxyphenyl)-6-[(1R,6R)-3-methyl-6-prop-1-en-2-ylcyclohex-2-en-1-yl]chromen-4-one
CAS Number:
1914963-20-4
Molecular Formula:
C25H24O5
![Bis(N,N''-dimethylpiperazine)tetra[copper(I) iodide] structure](https://static.chemtradehub.com/structs/140/1401708-91-5-2b86.webp "Bis(N,N''-dimethylpiperazine)tetra[copper(I) iodide] structure")
Bis(N,N''-dimethylpiperazine)tetra[copper(I) iodide]
CAS Number:
1401708-91-5
Molecular Formula:
C12H28Cu4I4N4
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