Spring-like motion caused large anisotropic thermal expansion in nonporous M(eim)2 (M = Zn, Cd)

Literature Information

Publication Date 2017-07-11
DOI 10.1039/C7CP03937A
Impact Factor 3.676
Authors

Zhanning Liu, Chenxi Liu, Qiang Li, Jun Chen, Xianran Xing


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Abstract

Two nonporous coordination polymers were found to possess large anisotropic thermal expansion, which was derived from the flexible structures. A “spring-like” thermal motion was proposed to illustrate the mechanism. Compound Cd(eim)2 (eim = 2-ethylimidazole) possesses large linear and reversible thermal expansion properties and the emission intensity shows a linear decrease with temperature, making it a candidate for thermo-responsive materials.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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