Aromatic and antiaromatic spherical structures: use of long-range magnetic behavior as an aromatic indicator for bare icosahedral [Al@Al12]− and [Si12]2− clusters
Literature Information
R. Bruce King
The long-range characteristics of the induced magnetic field in the bare icosahedral [Al@Al12]− and [Si12]2− clusters reveal inherent characteristics for spherical aromatic and antiaromatic systems. Here, we extend the shielding cone property to these highly symmetrical inorganic examples to achieve a suitable indicator for aromaticity as a reliable method for evaluating the aromaticity of clusters containing interstitial atoms.
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