![1-{[5-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-2-thienyl]methyl}piperidine structure](https://static.chemtradehub.com/structs/121/1218790-44-3-baef.webp "1-{[5-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-2-thienyl]methyl}piperidine structure")
1-{[5-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-2-thienyl]methyl}piperidine
CAS Number:
1218790-44-3
Molecular Formula:
C16H26BNO2S
Alkyl substituted poly(p-phenylene vinylene)s by ring opening metathesis polymerisation
Literature Information
Publication Date
2016-08-18
DOI
10.1039/C6PY01186A
Impact Factor
5.582
Authors
Benjamin J. Lidster, Dharam R. Kumar, Andrew M. Spring, Chin-Yang Yu, Michael L. Turner
View Original
Abstract
The ring opening metathesis polymerisation (ROMP) of three n-octyl substituted [2.2]paracyclophane-1,9-dienes, initiated by Grubbs ruthenium carbene complexes is reported. The molecular weight of the resulting alkyl-substituted poly(p-phenylene vinylene)s is determined by the monomer to initiator ratio and the polymers are isolated with relatively narrow polydispersities and control of the end groups. Only the pseudo-geminal isomer of the tetra-alkyl substituted [2.2]paracyclophane-1,9-diene was susceptible to ROMP. The optical properties of the two series of polymers was investigated.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
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3-(benzotriazol-1-yl)-N-[[2-[(3-bromophenyl)methoxy]phenyl]methylideneamino]propanamide
CAS Number:
5595-78-8
Molecular Formula:
C32H52O2
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