N-Ferrocenylsulfonyl-2-methylaziridine: the first ferrocene monomer for the anionic (co)polymerization of aziridines
Literature Information
Publication Date
2016-07-21
DOI
10.1039/C6PY01019A
Impact Factor
5.582
Authors
Tatjana Homann-Müller, Elisabeth Rieger, Arda Alkan, Frederik R. Wurm
View Original
Abstract
N-Ferrocenylsulfonyl-2-methylaziridine (fcMAz) is synthesized in a convenient three-step protocol from ferrocene. It represents the first aziridine-based monomer suitable for the anionic polymerization, carrying a ferrocenyl-substituent. Sulfonamide-activated aziridines can undergo (mostly living) anionic polymerization and fcMAz is also the first example of a functional sulfonamide-based aziridine monomer. It can be polymerized with different initiators to homo and copolymers (block or statistical) with adjustable molecular weights. The homopolymer is insoluble in common organic solvents, while the copolymers with other aziridines are soluble and exhibit molecular weight dispersities of 1.1–1.5. FcMAz thus broadens the scope of ferrocenyl-containing polymers and may be combined with other anionic polymerization techniques in the future.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
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Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
5-(6-Methoxy-1-benzofuran-2-yl)-2-(3-methyl-2-buten-1-yl)-1,3-benzenediol
CAS Number:
1017277-40-5
Molecular Formula:
C20H20O4
2-(5-Bromo-2-methyl-2H-indazol-3-yl)-2-propanol
CAS Number:
1823787-20-7
Molecular Formula:
C11H13BrN2O
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