A new route to achieve the side-chain-type sulfone-containing polysiloxanes via sulfide oxidation-induced cleavage and rearrangement of Si–O–Si bonds with fine selectivity toward cyclosiloxanes
Literature Information
Publication Date
2016-08-08
DOI
10.1039/C6PY01000H
Impact Factor
5.582
Authors
Zhiming Gou, Yujing Zuo, Jinwan Qi, Zhaoyue Li, Shengyu Feng
View Original
Abstract
A novel approach, with high selectivity, to obtain novel polysiloxanes containing sulfone groups from sulfur-bridged cyclosiloxane monomers was carried out without the use of catalysts; instead, sulfur oxidation was performed. The sulfide oxidation reaction can induce ring-opening polymerization of the cyclosiloxanes through cleavage and rearrangement of Si–O–Si bonds. Our findings present novel insights to synthesize new polysiloxanes.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
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