![3-[7-Amino-3-(3-pyridinyl)pyrazolo[1,5-a]pyrimidin-6-yl]phenol structure](https://static.chemtradehub.com/structs/861/861249-77-6-025b.webp "3-[7-Amino-3-(3-pyridinyl)pyrazolo[1,5-a]pyrimidin-6-yl]phenol structure")
3-[7-Amino-3-(3-pyridinyl)pyrazolo[1,5-a]pyrimidin-6-yl]phenol
CAS Number:
861249-77-6
Molecular Formula:
C17H13N5O
Cationic polymerization of p-methylstyrene in selected ionic liquids and polymerization mechanism
Literature Information
Publication Date
2016-06-21
DOI
10.1039/C6PY00796A
Impact Factor
5.582
Authors
View Original
Abstract
Cationic polymerization of p-methylstyrene (p-MeSt) in imidazolium-based [NTf2−1] ionic liquids (ILs) was investigated. The effects of the anions, cations, and alkyl chain length of ILs on p-MeSt solubility and viscosity were comprehensively studied. The COSMO-RS method, which is a valuable tool for screening and selecting ILs, was also applied to identify the most suitable solvent for p-MeSt cationic polymerization. The results revealed that p-MeSt cationic polymerization proceeded in a milder exothermic manner in ILs than in a traditional organic solvent. Controlled polymerizations were achieved in [Bmim][NTf2] with a CumOH/BF3OEt2 initiating system at −25 °C when 2,6-di-tert-butylpyridine was introduced. The cationic polymerization mechanism of p-MeSt in ILs was proposed on the basis of the results of density functional theory and the terminal structures of polymers.
Related Literature
Selective conversion of hydroxymethylfurfural to diformylfuran using copper hydroxide nitrate with various nano-structures: a comparative study
Bing-Cheng Li, Jechan Lee, Eilhann Kwon, Bui Xuan Thanh, Chia-Hua Lin, Kun-Yi Andrew Lin
2021-11-22
Paper
DOI: 10.1039/D1SE01443A
Highly ionic conductive and mechanically strong MXene/CNF membranes for osmotic energy conversion
Zhe Sun, Zongxia Gao, Zhu Shan, Liangmao Xu
2021-12-07
Paper
DOI: 10.1039/D1SE01729B
Decoding the charge carrier dynamics in triple cation-based perovskite solar cells
Mohd Taukeer Khan, Naveen Harindu Hemasiri
2021-10-26
Paper
DOI: 10.1039/D1SE01398J
A graphitic carbon nitride metal-free visible light photocatalyst with controllable carbon self-doping towards efficient hydrogen evolution
Lin Lei, Weijia Wang, Zhengfeng Xie, Xiaobo Wu, Arun Kumar Yadav, Huiqing Fan
2021-09-02
Paper
DOI: 10.1039/D1SE01244D
The role of nitrogen and sulfur dual coordination of cobalt in Co-N4−xSx/C single atom catalysts in the oxygen reduction reaction
Asnake Sahele Haile, Heine Anton Hansen, Weldegebriel Yohannes, Yedilfana Setarge Mekonnen
2021-11-16
Paper
DOI: 10.1039/D1SE01654G
Opportunities in Na/K [hexacyanoferrate] frameworks for sustainable non-aqueous Na+/K+ batteries
Ashwani Tyagi, Nagmani, Sreeraj Puravankara
2021-12-03
Review Article
DOI: 10.1039/D1SE01653A
ITIC derivative acceptors for ternary organic solar cells: fine-tuning of absorption bands, LUMO energy levels, and cascade charge transfer
Seungyun Baik, Dong Won Kim, Hyun-Sik Kang, Seung Hwa Hong, Sungjin Park, Byeong-Kwan An, Soo Young Park
2021-11-17
Paper
DOI: 10.1039/D1SE01429C
Controlling the carrier density in niobium oxynitride BaNbO2N via cation doping for efficient photoelectrochemical water splitting under visible light
Takafumi Iwai, Akinobu Nakada, Masanobu Higashi, Hajime Suzuki, Osamu Tomita
2021-10-25
Paper
DOI: 10.1039/D1SE01272J
Plasma enhanced anti-coking performance of Pd/CeO2 catalysts for the conversion of methane
Xiucui Hu, Yadi Liu, Liguang Dou, Yuan Gao, Xin Tu
2021-11-10
Paper
DOI: 10.1039/D1SE01441B
You might also like
Compound Q&A
What precautions should be taken when handling 2-Methyl-2-propanyl 5-amino-2-thiophenecarboxylate (CAS: 1498311-57-1)?
When handling 2-Methyl-2-propanyl 5-amino-2-thiophenecarboxylate (CAS: 1498311-5...
1498311-57-12-Methyl-2-propanyl ...
Compound Q&A
What are the physical and chemical properties of 5-Bromo-1,2-dichloro-3-fluorobenzene (CAS: 1000572-93-9)?
5-Bromo-1,2-dichloro-3-fluorobenzene (CAS: 1000572-93-9) is a crystalline solid ...
1000572-93-95-Bromo-1,2-dichloro...
Compound Q&A
How should (2R)-2-Amino-2-(4-bromophenyl)ethanol (CAS: 354153-64-3) be stored?
(2R)-2-Amino-2-(4-bromophenyl)ethanol (CAS: 354153-64-3) should be stored in a c...
354153-64-3(2R)-2-Amino-2-(4-br...
Compound Q&A
What regulatory guidelines apply to Methyl 4-(aminomethyl)tetrahydro-2H-pyran-4-carboxylate hydrochloride (CAS: 362707-24-2)?
Methyl 4-(aminomethyl)tetrahydro-2H-pyran-4-carboxylate hydrochloride (CAS: 3627...
362707-24-2Methyl 4-(aminomethy...
Compound Q&A
What are the main uses of 1,4-dimethyl-1H-pyrazole-5-sulfonyl chloride (CAS: 1174834-52-6)?
1,4-Dimethyl-1H-pyrazole-5-sulfonyl chloride is primarily used as an intermediat...
1174834-52-61,4-dimethyl-1H-pyra...
Compound Q&A
Is Dinaphtho[1,2-b:2',1'-d]furan (CAS: 239-69-0) safe?
Dinaphtho[1,2-b:2',1'-d]furan is generally safe when handled with appropriate pe...
239-69-0Dinaphtho[1,2-b:2',1...
Compound Q&A
What is the market or research trend for 7-Methyl-7,9-dihydro-1H-purine-2,6,8(3H)-trione (CAS: 612-37-3)?
The market for 7-Methyl-7,9-dihydro-1H-purine-2,6,8(3H)-trione (CAS: 612-37-3) i...
612-37-37-Methyl-7,9-dihydro...
Compound Q&A
What are the physical and chemical properties of 2-(4-Chlorophenyl)malonaldehyde (CAS: 205676-17-1)?
2-(4-Chlorophenyl)malonaldehyde (CAS: 205676-17-1) is a colorless or light yello...
205676-17-12-(4-Chlorophenyl)ma...
Compound Q&A
How is 2-Methylchrysene (CAS: 3351-32-4) typically synthesized?
2-Methylchrysene (CAS: 3351-32-4) is typically synthesized via the reaction of c...
3351-32-42-Methylchrysene
Compound Q&A
Is N-(6-aminopyrimidin-4-yl)acetamide (CAS: 89533-23-3) safe?
N-(6-aminopyrimidin-4-yl)acetamide (CAS: 89533-23-3) is generally considered saf...
89533-23-3N-(6-aminopyrimidin-...
Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
(5Z,11alpha,13E,15R)-11,15-Dihydroxy-15-methyl-9-oxoprosta-5,13-dien-1-oic acid
CAS Number:
55028-70-1
Molecular Formula:
C21H34O5
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.