Infrared amplified spontaneous emission from the 0 +g (3P0) and 0 +g (1D2) ion-pair states of molecular bromine
Literature Information
Shoma Hoshino, Mitsunori Araki, Takashi Ishiwata, Koichi Tsukiyama
We report the observation of amplified spontaneous emission for the first time from the 0+g (3P0) and 0+g (1D2) ion-pair states of Br2 by using an optical–optical double resonance technique through the B 3Π(0+u) valence state as the intermediate state. The strong infrared emission propagating along the incident laser radiation is assigned to the parallel ASE transitions from the 0+g ion-pair states down to the nearby 0+u ion-pair states. The subsequent UV fluorescence from the 0+u states to the high vibrational levels of the ground state is also observed. By the Franck–Condon simulation of the cascade UV fluorescence, we determine the vibrational distributions in the 0+u states populated by ASE, which are consistent with the intensity distribution in the dispersed infrared ASE spectrum. The lifetimes of the relevant ion-pair states are evaluated by analyzing the temporal profiles of the UV fluorescence.
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.












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