Determination of toluene hydrogenation kinetics with neutron diffraction
Literature Information
Sarayute Chansai, Haresh G. Manyar, Lynn F. Gladden, Daniel T. Bowron, Tristan G. A. Youngs, Christopher Hardacre
Total neutron scattering has been used to follow the hydrogenation of toluene-d8 to methylcyclohexane-d14 over 3 wt% platinum supported on highly ordered mesoporous silica (MCM-41) at 298 K and under 150 mbar D2 pressure. The detailed kinetic information so revealed indicates that liquid reorganisation inside pores is the slowest step of the whole process. Additionally, the results were compared with the reaction performed under 250 mbar D2 pressure as well as with toluene-h8 hydrogenation using D2 at 150 mbar.
Recommended Journals

Bio-Medical Materials and Engineering

Main Group Metal Chemistry

Current Medicinal Chemistry

Chemistry of Materials

Cement and Concrete Composites

Construction and Building Materials

Journal of Physical Organic Chemistry

Advances in Cement Research

Advanced Composite Materials

Computational Materials Science
Related Literature
Oxygen and carbon dioxide dual gas-responsive homopolymers and diblock copolymers synthesized via RAFT polymerization
Xue Jiang, Guolin Lu, Huang Xiaoyu
DOI: 10.1039/C6PY02004F
Effect of epoxy monomer structure on the curing process and thermo-mechanical characteristics of tri-functional epoxy/amine systems: a methodology combining atomistic molecular simulation with experimental analyses
Liang Gao, Qingjie Zhang, Hao Li, Siruo Yu, Weihong Zhong, Gang Sui, Xiaoping Yang
DOI: 10.1039/C7PY00063D
A known photoinitiator for a novel technology: 2-(4-methoxystyryl)-4,6-bis(trichloromethyl)-1,3,5-triazine for near UV or visible LED
Jing Zhang, Pu Xiao, Fabrice Morlet-Savary, Bernadette Graff, Jean Pierre Fouassier, Jacques Lalevée
DOI: 10.1039/C4PY00770K
The impact of the molecular weight on the electrochemical properties of poly(TEMPO methacrylate)
Kai Zhang, Jiyu Fan, Michael J. Monteiro, Zhongfan Jia
DOI: 10.1039/C7PY00151G
Dendrimer–doxorubicin conjugate as enzyme-sensitive and polymeric nanoscale drug delivery vehicle for ovarian cancer therapy
Chengyuan Zhang, Dayi Pan, Kui Luo, Ning Li, Chunhua Guo, Xiuli Zheng, Zhongwei Gu
DOI: 10.1039/C4PY00601A
Ultra-sensitive detection of explosives in solution and film as well as the development of thicker film effectiveness by tetraphenylethene moiety in AIE active fluorescent conjugated polymer
Khama Rani Ghosh, Sukanta Kumar Saha
DOI: 10.1039/C4PY00673A
The living anionic polymerization of activated aziridines: a systematic study of reaction conditions and kinetics
Elisabeth Rieger, Tassilo Gleede, Katja Weber, Angelika Manhart, Manfred Wagner, Frederik R. Wurm
DOI: 10.1039/C7PY00436B
Synthesis of highly branched polymers by reversible complexation-mediated copolymerization of vinyl and divinyl monomers
Hongjun Yang, Zhongrui Wang, Yulei Zheng, Wenyan Huang, Xiaoqiang Xue, Bibiao Jiang
DOI: 10.1039/C7PY00174F
Non-conventional fluorescent biogenic and synthetic polymers without aromatic rings
Yilin Zhang, Liguo Xu, Rongrong Hu, Kam Sing Wong, William A. Goddard, III
DOI: 10.1039/C7PY00154A
You might also like
What regulatory guidelines apply to 4-Amino-3-bromophenol (CAS: 74440-80-5)?
4-Amino-3-bromophenol (CAS: 74440-80-5) falls under the classification of a haza...
How should (17beta)-3-Oxoestr-4-en-17-yl acetate (CAS: 1425-10-1) be stored?
(17beta)-3-Oxoestr-4-en-17-yl acetate should be stored in a cool, dry place away...
What are the physical and chemical properties of 2-[(2,2-Diethoxyethyl)disulfanyl]-1,1-diethoxyethane (CAS: 76505-71-0)?
2-[(2,2-Diethoxyethyl)disulfanyl]-1,1-diethoxyethane (CAS: 76505-71-0) is a colo...
What is the market or research trend for 1-(β-D-ribofuranosyl)-1H-imidazo[4,5-c]pyridin-4-amine?
The market and research for 1-(β-D-ribofuranosyl)-1H-imidazo[4,5-c]pyridin-4-ami...
How should waste containing Conjugated Estrogen (CAS: 12126-59-9) be handled?
Waste containing Conjugated Estrogen (CAS: 12126-59-9) should be collected and d...
What is the market or research trend for Bis(2,2,2-trifluoroethyl) (methoxycarbonylmethyl)phosphonate?
The market for Bis(2,2,2-trifluoroethyl) (methoxycarbonylmethyl)phosphonate (CAS...
Are there alternatives to 3,4'-Di-O-methylellagic acid (CAS: 57499-59-9) in synthesis?
There are several alternatives to 3,4'-Di-O-methylellagic acid (CAS: 57499-59-9)...
What regulatory guidelines apply to 2-Chloro-N,N-dimethylpyridin-4-amine (CAS: 59047-70-0)?
2-Chloro-N,N-dimethylpyridin-4-amine (CAS: 59047-70-0) is regulated under the Gl...
What is cerium(3+);oxygen(2-);vanadium(5+) (CAS: 13597-19-8)?
Cerium(3+);oxygen(2-);vanadium(5+) (CAS: 13597-19-8) is a complex inorganic comp...
Is 7-Chloro-1-iodoisoquinoline (CAS: 1203579-27-4) safe?
7-Chloro-1-iodoisoquinoline (CAS: 1203579-27-4) is generally considered safe whe...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.




