Analytically useful blue chemiluminescence from a water-soluble iridium(iii) complex containing a tetraethylene glycol functionalised triazolylpyridine ligand

Literature Information

Publication Date 2016-02-26
DOI 10.1039/C6AN00141F
Impact Factor 4.616
Authors

Zoe M. Smith, Emily Kerr, Egan H. Doeven, Neil W. Barnett, Paul S. Donnelly, Stephen J. Haswell, Paul S. Francis


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Abstract

We examine [Ir(df-ppy)2(pt-TEG)]+ as the first highly water soluble, blue-luminescent iridium(III) complex for chemiluminescence detection. Marked differences in selectivity were observed between the new complex and the conventional [Ru(bpy)3]2+ reagent, which will enable this mode of detection to be extended to new areas of application.

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