![2-Methyl-2-propanyl 4-oxo-3,9-diazabicyclo[4.2.1]nonane-9-carboxylate structure](https://static.chemtradehub.com/structs/131/1312456-05-5-9a15.webp "2-Methyl-2-propanyl 4-oxo-3,9-diazabicyclo[4.2.1]nonane-9-carboxylate structure")
2-Methyl-2-propanyl 4-oxo-3,9-diazabicyclo[4.2.1]nonane-9-carboxylate
CAS Number:
1312456-05-5
Molecular Formula:
C12H20N2O3
Synthesis of stereodiblock polyisoprene consisting of cis-1,4 and trans-1,4 sequences by using a neodymium catalyst: change of the stereospecificity triggered by an aluminum compound
Literature Information
Publication Date
2016-01-12
DOI
10.1039/C5PY01872B
Impact Factor
5.582
Authors
Ryo Tanaka, Kaede Yuuya, Hiroki Sato, Peter Eberhardt, Yuushou Nakayama, Takeshi Shiono
View Original
Abstract
The first example of the synthesis of stereodiblock polyisoprene which consists of cis-1,4 and trans-1,4 sequences was achieved by using a neodymium catalyst. The stereospecificity was controlled by the ratio of Bu2Mg and modified methylaluminoxane (MMAO), and by sequential addition of Bu2Mg and MMAO, a geometrically well-defined stereodiblock polymer was obtained.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
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CAS Number:
874289-09-5
Molecular Formula:
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