![[2',6'-bis(propan-2-yloxy)-[1,1'-biphenyl]-3-yl]dicyclohexylphosphane structure](https://static.chemtradehub.com/structs/787/787618-22-8-dda2.webp "[2',6'-bis(propan-2-yloxy)-[1,1'-biphenyl]-3-yl]dicyclohexylphosphane structure")
[2',6'-bis(propan-2-yloxy)-[1,1'-biphenyl]-3-yl]dicyclohexylphosphane
CAS Number:
787618-22-8
Molecular Formula:
C30H43O2P
Modification of chitosan with polystyrene and poly(n-butyl acrylate) via nitroxide-mediated polymerization and grafting from approach in homogeneous media
Literature Information
Publication Date
2015-02-13
DOI
10.1039/C5PY00028A
Impact Factor
5.582
Authors
R. Champagne-Hartley, E. Saldívar-Guerra, M. F. Cunningham
View Original
Abstract
Chitosan (CTS) modification with polystyrene (PS) and poly(n-butyl acrylate) (PnBA) via nitroxide-mediated polymerization (NMP) and a grafting from approach is reported. CTS was first functionalized with glycidyl methacrylate (GMA) and then converted into a macroalkoxyamine by intermolecular 1,2 radical addition of either 2,2,5-trimethyl-3-(1-phenylethoxy)-4-phenyl-3-azahexane (TIPNO-based alkoxyamine the “Universal Alkoxyamine”, UA) or the SG1-based BlocBuilder (BB) alkoxyamine. Graft polymerizations of styrene and n-butyl acrylate were conducted, using homogeneous media to ensure uniform grafting onto the CTS backbone. The graft modified CTS based materials were analysed by 1H-NMR, TGA and FT-IR.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
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1-(Hexopyranosyloxy)-4a,5-dihydroxy-7-methyl-1,4a,5,6,7,7a-hexahydrocyclopenta[c]pyran-7-yl 3-phenylacrylate
CAS Number:
19210-12-9
Molecular Formula:
C24H30O11
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