Classical group theory adapted to the mechanism of Pt3Ni nanoparticle growth: the role of W(CO)6 as the “shape-controlling” agent

Literature Information

Publication Date 2015-11-16
DOI 10.1039/C5CP05060J
Impact Factor 3.676
Authors

M. Radtke, A. Ignaszak


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Abstract

Classical group theory was applied to prove the Pt3Ni crystallographic transformation from Platonic cubic to Archimedean cuboctahedral structures and the formation of Pt3Ni polypods. The role of W(CO)6 as a shape-controlling agent is discussed with respect to the crystallographic features of the clusters and superstructures generated as control samples.

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