One-pot synthesis of indolizine functionalized nanohyperbranched polyesters with different nano morphologies and their fluorescent response to anthracene

Literature Information

Publication Date 2014-12-05
DOI 10.1039/C4PY01529K
Impact Factor 5.582
Authors

Xiaoxia Wang, Fanyang Zeng, Can Jin, Yuliang Jiang, Qiaorong Han, Bingxiang Wang, Zhenye Ma


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Abstract

The structurally controllable hyperbranched HBPE–CIDAs (HBPE modified with CIDA units) were synthesized by modifying the periphery of the second generation hyperbranched polyester (HBPE) with 1-cyanoindolizine-3-carboxylic acid (CIDA) groups via a one-pot synthesis. The structures and self-assembly behaviors of HBPE–CIDAs were established by combined studies of FFT-IR, NMR, TEM, SEM, AFM and XRD. Furthermore, host–guest recognition of HBPE–CIDAs was investigated by fluorescence studies. The results indicated that the HBPE–CIDA4 nanospindles have weaker response to various metal ions while having better selectivity to anthracene through π–π stacking interactions than the HBPE–CIDA1 nanospheres.

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Polymer Chemistry

Polymer Chemistry
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Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.

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