Transition metalborylene complexes: boron analogues of classical organometallic systems

Literature Information

Publication Date 2009-01-07
DOI 10.1039/B816042B
Impact Factor 6.222
Authors

Dragoslav Vidovic, Glesni A. Pierce, Simon Aldridge


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Abstract

In the ten years since the first examples of terminal borylene complexes were reported, rapid advances in the chemistry of this ligand class have been made, and parallels emerged with classical organometallic ligand systems (such as carbenes, vinylidenes and even CO) as well as with other subvalent main group ligand systems. This article reviews key developments in synthetic, structural and reaction chemistry, with particular attention focusing on recent discoveries in the field.

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