![N-[2,6-Di(9-anthryl)-4-oxido-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl]-1,1,1-trifluoromethanesulfonamide structure](https://static.chemtradehub.com/structs/122/1227374-64-2-cdb5.webp "N-[2,6-Di(9-anthryl)-4-oxido-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl]-1,1,1-trifluoromethanesulfonamide structure")
N-[2,6-Di(9-anthryl)-4-oxido-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl]-1,1,1-trifluoromethanesulfonamide
CAS Number:
1227374-64-2
Molecular Formula:
C49H37F3NO5PS
Effect of monomers’ structure on self-acid-assisted polycondensation for the synthesis of poly(3,4-ethylenedioxythiophene) and homopolythiophene
Literature Information
Publication Date
2014-10-27
DOI
10.1039/C4PY01070A
Impact Factor
5.582
Authors
Chuong Tusy, Kang Jiang, Kai Peng, Lili Huang, Jiangbin Xia
View Original
Abstract
Poly(3,4-ethylenedioxythiophene) (PEDOT) and thiophene based homopolymers were synthesized by self-acid-assisted polycondensation (SAAP) through mono-halogen substituted thiophene derivative monomers. Detailed characterization of the obtained polymers was carried out by X-ray diffraction (XRD), cyclic voltammetry (CV), infrared spectrum (IR), UV-Vis absorbance spectroscopy, fluorescence spectroscopy (FR) and thermogravimetric analysis (TGA). Most synthesized monomers can be spontaneously polymerized successfully through a simple annealing process at moderate temperature, indicating that they are suitable for SAAP. Moreover, our results reveal that substituted halogen (bromo or iodo) positions play an important role in SAAP, which may pave a wide path for exploring other conjugated polythiophenes through such a facile method.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
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