(2R,2'R)-1,1'-Bis(2-pyridinylmethyl)-2,2'-bipyrrolidine tetrahydrochloride
CAS Number:
1228077-88-0
Molecular Formula:
C20H30Cl4N4
Gated molecular baskets
Literature Information
Publication Date
2014-06-13
DOI
10.1039/C4CS00140K
Impact Factor
54.564
Authors
Keith Hermann, Yian Ruan, Alex M. Hardin, Christopher M. Hadad, Jovica D. Badjić
View Original
Abstract
In this review, we describe the construction of gated molecular baskets, discuss their mechanism of action in regulating the exchange of guests and illustrate the potential of these concave hosts to act as catalysts for controlling chemical reactions. Importantly, a number of computational and experimental studies have suggested that gated baskets ought to unfold their gates at the rim for permitting the passage of guests to/from their inner space. These dynamic hosts are therefore offered as useful models for investigating the process of gating in artificial systems. Furthermore, gated baskets should permit examining the benefit of controlling the rate by which reactants access a gated catalyst for promoting chemical reactions occurring in its confined space.
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Source Journal
Chemical Society Reviews
CiteScore:
80.8
Self-citation Rate:
1.2%
Articles per Year:
250
Chem Soc Rev publishes review articles covering important topics at the forefront of the chemical sciences. Reviews should be of the very highest quality and international impact. We particularly encourage international and multidisciplinary collaborations among our authors. Our scope covers the breadth of the chemical sciences, including interdisciplinary topics where the article has a basis in chemistry. Topics include: Analytical chemistry Biomaterials chemistry Bioorganic/medicinal chemistry Catalysis Chemical Biology Coordination Chemistry Crystal Engineering Energy Sustainable chemistry Green chemistry Inorganic chemistry Inorganic materials Main group chemistry Nanoscience Organic chemistry Organic materials Organometallics Physical chemistry Supramolecular chemistry Synthetic methodology Theoretical and computational chemistry
Recommended Compounds
(4aS,10aS)-7-Isopropyl-1,4a-dimethyl-5,8-dioxo-3,4,4a,5,8,9,10,10a-octahydro-2-phenanthrenecarboxylic acid
CAS Number:
142950-86-5
Molecular Formula:
C20H24O4
2-Amino-2-(4-(pyridin-2-YL)phenyl)acetic acid hydrochloride
CAS Number:
1135818-89-1
Molecular Formula:
C13H13ClN2O2
![N-[(6-Bromo-3-pyridinyl)methyl]ethanamine structure](https://static.chemtradehub.com/structs/120/120740-05-8-ca55.webp "N-[(6-Bromo-3-pyridinyl)methyl]ethanamine structure")
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